From IIT Kanpur

[17] S. Raje,* K. Mani and R. Angamuthu.* Solvent-Free Solid-Phase Synthesis and Reactivity Studies of New Nickel(II) Borohydrides. J. Organomet. Chem. 2019, 0, 0000.

[16] S. Raje* and R. Angamuthu.* Solvent-Free Synthesis and Reactivity of Nickel(II) Borohydride and Nickel(II) Hydride. Green Chemistry, 2019, 21, 2752.

[15]. S. Raje, K. Mani, P. Kandasamy, R. J. Butcher and R. Angamuthu. Bioinspired Oxidative Cleavage of Aliphatic C-C Bond Utilizing Aerial Oxygen by Nickel Acireductone Dioxygenase Mimics. Eur. J. Inorg. Chem. 2019, 2164-2167.

[14]. D. Bharadwaj and R. Angamuthu. Cryptand based fluorescence signalling systems for transition, inner-transition and main group metal ions: modulation of the PET process through attachment of electron-withdrawing and electron donating groups. J. Photochem. Photobiol., A: Chemistry,  369 (2019) 1-7.

[13]. M. Chahal, K. Mani, C. S. Lodhi, R. J. Butcher, R. Angamuthu* and S. Raje*. Metal Dependent Formation of Imidazolidine or Hemiaminal Ether Complexes from Multicomponent One-pot Reactions. ChemistrySelect 2018, 3, 9960-9964.

[12]. S. Raje* and R. Angamuthu. Tetranuclear nickel cubane cluster formed by the hydrolysis of nickel koneramine complex. Inorg. Chim. Acta., 483 (2018) 258–261.

[11]. Y. Zhao, X. Yu, H. Hu, X. Hu, S. Raje, R. Angamuthu, C.-H. Tung, W. Wang. Synthetic [FeFe]-H2ase models bearing phosphino thioether chelating ligands.  Chinese Chemical Letters, 29 (2018) 1651-1655.

[10]. S. Raje, N. Mondivagu, M. Chahal, R. J. Butcher, R. Angamuthu. Mechanism of Evolution of Koneramine Complexes from One‐Pot Reactions: Snapshots of Intermediates Offer Facile Routes to New Dipicolylamines.  Chem. Asian. J., 2018, 13, 1458-1466.

[9]. S. Mehrotra, S. Raje, A. K. Jain, A. Jain, P. Kandasamy, R. J. Butcher, R. Angamuthu. A Quest towards Eccentric Piedfort Pairs.  ChemistrySelect, 2018, 3, 4844-4850.

[8]. A. Zhang, S. Raje, J. Liu, X. Li, R. Angamuthu, C.-H. Tung, W. Wang. Nickel-Mediated Stepwise Transformation of CO to Acetaldehyde and Ethanol.  Organometallics, 2017, 3135−3141.

[7]. S. Raje, K. Mani, M. M. Parsutkar, R. Angamuthu. Metal ions as external stimuli in stereoselective self-sorting of koneramines and thiokoneramines.  New J. Chem., 2017, 12303-12308.

[6]. S. Mehrotra, S. Raje, A. K. Jain, R. Angamuthu. Benzimidazolines Convert Sulfur Dioxide to Bisulfate at Room Temperature and Atmospheric Pressure Utilizing Aerial Oxygen.  ACS Sustainable Chem. Eng., 2017, 5, 6322-6328.

[5]. X. Chu, X. Yu, S. Raje, R. Angamuthu, J. Ma, C.-H. Tung, W. Wang. Synthetic [NiFe] models with a fluxional CO ligand.  Dalton Trans., 2017, 46, 13681-13685.

[4]. X. Chu, X. Xu, H. Su, S. Raje, R. Angamuthu, C.-H. Tung, W. Wang. Heteronuclear assembly of Ni-Cu dithiolato complexes: synthesis, structures, and reactivity studies.  Inorg. Chem. Front., 2017, 4, 706-711.

[3]. S. Raje, S. Gurusamy, A. Koner, S. Mehrotra, S. J. Jennifer, P. G. Vasudev, R. J. Butcher, R. Angamuthu. Multicomponent One-pot Reactions Towards the Synthesis of Stereoisomers of Dipicolylamine Complexes.  Chem. Asian. J., 2016, 11, 128-135.

[2]. S. Mehrotra, R. J. Butcher, R. Angamuthu. Benzothiazoline Converts SO2 to Sulfuric Acid en Route to Benzothiazole.  ACS Sustainable Chem. Eng., 2016, 6517−6523.

[1]. S. Mehrotra, R. Angamuthu. Janus head type lone pair…π…lone pair and S…F…S interactions in retaining hexafluorobenzene.  Crystengcomm, 2016, 18, 4438-4444.



[8]  R. Angamuthu, C.-S. Chen, T. R. Cochrane, D. L. Gray, D. Schilter, O. A. Ulloa, T. B. Rauchfuss. N-Substituted Derivatives of the Azadithiolate Cofactor from the [FeFe] Hydrogenases: Stability and Complexation. Inorg. Chem. 2015, 54, 5717-5724.

[7]  G. M. Chambers, R. Angamuthu, D. L. Gray, T. B. Rauchfuss. Organo Ruthenium–Nickel Dithiolates with Redox-Responsive Nickel Sites. Organometallics 2013, 32, 6324-6329.

[6]  R. Angamuthu, M. E. Carroll, M. Ramesh, T. B. Rauchfuss. A New Route to Azadithiolato Complexes. Eur. J. Inorg. Chem. 2011, 1029-1032.


PhD (Leiden, NL)

[5]  R. Angamuthu, P. Byers, M. Lutz, A. L. Spek, E. Bouwman. Electrocatalytic carbon dioxide Conversion to Oxalate by a Copper Complex. Science 2010, 327, 313-315.

[4]  R. Angamuthu, L. L. Gelauff, M. A. Siegler, A. L. Spek, E. Bouwman. A molecular cage of nickel(II) and copper(I): a [{Ni(L)(2)}(2)(CuI)(6)] cluster resembling the active site of nickel-containing enzymes. Chem. Commun. 2009, 2700-2702.

[3]  R. Angamuthu, E. Bouwman. Reduction of protons assisted by a hexanuclear nickel thiolate metallacrown: protonation and electrocatalytic dihydrogen evolution. Phys. Chem. Chem. Phys. 2009, 11, 5578-5583.

[2]  R. Angamuthu, H. Kooijman, M. Lutz, A. L. Spek, E. Bouwman. Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks.  Dalton Trans. 2007, 4641-4643.


MSc (Bharathidasan, Trichy)

[1]  R. Angamuthu, R. Venugopal, U. M. Palanisamy, B. Ramalingam, C. A. Kilner, M. A. Halcrow, P. Mallayan. Copper(II) complexes of tridentate pyridylmethylethylenediamines: Role of ligand steric hindrance on DNA binding and cleavage. J. Inorg. Biochem. 2005, 99, 1717-1732.