Metal and Solvent–Dependent Formation of Imidazolidine or Hemiaminal Ether Complexes

S. Ghosh, R. J. Butcher, R. Angamuthu*

Inorg. Chim. Acta, 2024, 570, 122167.

Late-stage Ligand Modification After Coordination Strengthens Stereoselectively Self-Assembled Hemiaminal Ether Complexes 

S. Raje, A. Koner, S. Ghosh, R. J. Butcher, L. Mathivathanan, M. Sundararajan, R. Angamuthu*

Chem. Asian. J. 2023, e202300706.

Mechanochemical Synthesis and Reactivity of a Stable Nickel Borohydride

S. Raje,* K. Mani, S. Dinesh, A. Yadav, M. Chahal, R. J. Butcher, and R. Angamuthu*

Helv. Chim. Acta 2023, 106, e202200188

Triazine-based eccentric Piedfort units towards a single source hydrogen-bonded network. 

S. Mehrotra, S. Raje, A. K. Jain, R. J. Butcher and  R. Angamuthu*

Chem. Commun., 2022, 58, 11815–11818. 

Investigating the photosensitivity of koneramines for cell imaging and therapeutic applications.

S. Ghosh,*  A. Akhir,  D. Saxena, S. Singh, S. Sivakumar, S. Chopra* and  R. Angamuthu* 

Dalton Trans., 2022, 51, 15659 – 15668.

Air-stable nickel(II) borohydrides as prohydrides: Reactions with halocarbons and aerial carbon dioxide

K. Mani, P. Pal, K. Anandababu, S. Raje,* R. Angamuthu*

Inorg. Chim. Acta, 2021, 526, 120526

Binding enabled catalytic activation of SO₂ by copper koneramine complexes under ambient conditions.

M. Chahal, S. Raje,* G. Kotana and R. Angamuthu*

Green Chemistry, 2019, 21, 6372-6380. 

Reductive Coupling of Bridging Diaryl Ligands in Half-Sandwich Cobalt(II) Dimers: Revisiting Triple-Decker Cobalt(I) Complexes.

S. Zhang, Y. Song, X. He, R. Angamuthu,* C.-H. Tung, and W. Wang*

Organometallics 2019, 38, 3610-3616.

Solvent-Free Synthesis and Reactivity of Nickel(II) Borohydride and Nickel(II) Hydride. 

S. Raje* and R. Angamuthu* 

Green Chemistry, 2019, 21, 2752.

Bioinspired Oxidative Cleavage of Aliphatic C-C Bond Utilizing Aerial Oxygen by Nickel Acireductone Dioxygenase Mimics. 

S. Raje, K. Mani, P. Kandasamy, R. J. Butcher and R. Angamuthu* 

Eur. J. Inorg. Chem. 2019, 2164–2167

Cryptand-based fluorescence signalling systems for transition, inner-transition, and main group metal ions: Modulation of the PET process through the attachment of electron-withdrawing and electron-donating groups

D. Bharadwaj, R. Angamuthu*

J. Photochem. & Photobiol. A: Chem, 2019, 369, 1–7.

Mechanism of Evolution of Koneramine Complexes from One‐Pot Reactions: Snapshots of Intermediates Offer Facile Routes to New Dipicolylamines. 

S. Raje, N. Mondivagu, M. Chahal, R. J. Butcher, R. Angamuthu*

Chem. Asian. J., 2018, 13, 1458-1466. 

Synthetic [FeFe]-H₂ase models bearing phosphino thioether chelating ligands

Y. Zhao, X. Yu, H. Hu, X. Hu, S. Raje, R. Angamuthu, C-H. Tung, W. Wang*

Chinese Chem. Lett. 2018, 29, 1651–1655

Tetranuclear nickel cubane cluster formed by the hydrolysis of nickel koneramine complex

S. Raje,* R. Angamuthu

Inorg. Chim. Acta, 2018, 483, 258–261

A Quest towards Eccentric Piedfort Pairs

S. Mehrotra, S. Raje, A. K. Jain, A. Jain, P. Kandasamy, R. J. Butcher, and R. Angamuthu*

ChemistrySelect 2018, 3, 4844 – 4850

Metal Dependent Formation of Imidazolidine or Hemiaminal Ether Complexes from Multicomponent One-pot Reactions

M. Chahal, K. Mani, C. S. Lodhi, R. J. Butcher, S. Raje,* R. Angamuthu*

ChemistrySelect 2018, 3, 9960 – 9964

Nickel-Mediated Stepwise Transformation of CO to Acetaldehyde and Ethanol. 

A. Zhang, S. Raje, J. Liu, X. Li, R. Angamuthu, C.-H. Tung, W. Wang* 

Organometallics, 2017, 3135−3141. 

Benzimidazolines Convert Sulfur Dioxide to Bisulfate at Room Temperature and Atmospheric Pressure Utilizing Aerial Oxygen. 

S. Mehrotra, S. Raje, A. K. Jain, R. Angamuthu* 

ACS Sustainable Chem. Eng., 2017, 5, 6322-6328. 

Synthetic [NiFe] models with a fluxional CO ligand. 

X. Chu, X. Yu, S. Raje, R. Angamuthu, J. Ma, C.-H. Tung, W. Wang* 

Dalton Trans.,2017, 46, 13681-13685.

Metal Ions as External Stimuli in Stereoselective Self-Sorting of Koneramines and Thiokoneramines

S. Raje, K. Mani, M. M. Parsutkar and R. Angamuthu*

New J. Chem., 2017, 41, 12303

Heteronuclear assembly of Ni–Cu dithiolato complexes: synthesis, structures, and reactivity studies

X. Chu, X. Xu, H. Su, S. Raje, R. Angamuthu, C-H. Tung and W. Wang*

Inorg. Chem. Front., 2017, 4, 706

Janus head type lone pair–π–lone pair and S⋯F⋯S interactions in retaining hexafluorobenzene

S. Mehrotra and R. Angamuthu*

CrystEngComm, 2016, 18, 4438.

Multicomponent One-pot Reactions Towards the Synthesis of Stereoisomers of Dipicolylamine Complexes. 

S. Raje, S. Gurusamy, A. Koner, S. Mehrotra, S. J. Jennifer, P. G. Vasudev, R. J. Butcher, R. Angamuthu* 

Chem. Asian. J., 2016, 11, 128-135. 

Benzothiazoline Converts SO₂ to Sulfuric Acid en Route to Benzothiazole.

S. Mehrotra, R. J. Butcher, R. Angamuthu* 

ACS Sustainable Chem. Eng.,2016, 6517−6523. 

R. Angamuthu, C.-S. Chen, T. R. Cochrane, D. L. Gray, D. Schilter, O. A. Ulloa, T. B. Rauchfuss*

N-Substituted Derivatives of the Azadithiolate Cofactor from the [FeFe] Hydrogenases: Stability and Complexation.

Inorg. Chem. 2015, 54, 5717-5724.

G. M. Chambers, R. Angamuthu, D. L. Gray, T. B. Rauchfuss* 

Organo Ruthenium–Nickel Dithiolates with Redox-Responsive Nickel Sites. 

Organometallics 2013, 32, 6324-6329.

R. Angamuthu, M. E. Carroll, M. Ramesh, T. B. Rauchfuss* 

A New Route to Azadithiolato Complexes.

Eur. J. Inorg. Chem. 2011, 1029-1032.

R. Angamuthu, P. Byers, M. Lutz, A. L. Spek, E. Bouwman* 

Electrocatalytic carbon dioxide Conversion to Oxalate by a Copper Complex. 

Science 2010, 327, 313-315.

R. Angamuthu, L. L. Gelauff, M. A. Siegler, A. L. Spek, E. Bouwman* 

A molecular cage of nickel(II) and copper(I): a [{Ni(L)₂}₂(CuI)₆] cluster resembling the active site of nickel-containing enzymes. 

Chem. Commun. 2009, 2700-2702.

R. Angamuthu, E. Bouwman* 

Reduction of protons assisted by a hexanuclear nickel thiolate metallacrown: protonation and electrocatalytic dihydrogen evolution. 

Phys. Chem. Chem. Phys. 2009, 11, 5578-5583.

R. Angamuthu, H. Kooijman, M. Lutz, A. L. Spek, E. Bouwman* 

Hexanuclear [Ni₆L₁₂] metallacrown framework consisting of NiS₄ square-planar and NiS₅ square-pyramidal building blocks.  

Dalton Trans. 2007, 4641-4643.

R. Angamuthu, R. Venugopal, U. M. Palanisamy, B. Ramalingam, C. A. Kilner, M. A. Halcrow, P. Mallayan*

Copper(II) complexes of tridentate pyridylmethylethylenediamines: Role of ligand steric hindrance on DNA binding and cleavage.

J. Inorg. Biochem. 2005, 99, 1717-1732.