.* Chem. Commun., 2022, 58, 11815–11818. 

.* Dalton Trans., 2022, 51, 15659 – 15668.

Binding enabled catalytic activation of SO2 by copper koneramine complexes under ambient conditions. M. Chahal, S. Raje,* G. Kotana and R. Angamuthu.* Green Chemistry, 2019, 21, 6372-6380. 

Reductive Coupling of Bridging Diaryl Ligands in Half-Sandwich Cobalt(II) Dimers: Revisiting Triple-Decker Cobalt(I) Complexes. S. Zhang, Y. Song, X. He, R. Angamuthu,* C.-H. Tung, and W. Wang.* Organometallics 2019, 38, 3610-3616. 

Figure 1

Solvent-Free Synthesis and Reactivity of Nickel(II) Borohydride and Nickel(II) Hydride. S. Raje* and R. Angamuthu.* Green Chemistry, 2019, 21, 2752. 

Bioinspired Oxidative Cleavage of Aliphatic C-C Bond Utilizing Aerial Oxygen by Nickel Acireductone Dioxygenase Mimics. S. Raje, K. Mani, P. Kandasamy, R. J. Butcher and R. Angamuthu. Eur. J. Inorg. Chem. 2019, 2164-2167. 

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Mechanism of Evolution of Koneramine Complexes from One‐Pot Reactions: Snapshots of Intermediates Offer Facile Routes to New Dipicolylamines. S. Raje, N. Mondivagu, M. Chahal, R. J. Butcher, R. Angamuthu. Chem. Asian. J., 2018, 13, 1458-1466. 

 Description unavailable

Nickel-Mediated Stepwise Transformation of CO to Acetaldehyde and Ethanol. A. Zhang, S. Raje, J. Liu, X. Li, R. Angamuthu, C.-H. Tung, W. Wang. Organometallics, 2017, 3135−3141. 

Figure 1

Benzimidazolines Convert Sulfur Dioxide to Bisulfate at Room Temperature and Atmospheric Pressure Utilizing Aerial Oxygen. S. Mehrotra, S. Raje, A. K. Jain, R. Angamuthu.  ACS Sustainable Chem. Eng., 2017, 5, 6322-6328. 

Synthetic [NiFe] models with a fluxional CO ligand. X. Chu, X. Yu, S. Raje, R. Angamuthu, J. Ma, C.-H. Tung, W. Wang. Dalton Trans., 2017, 46, 13681-13685. 

Multicomponent One-pot Reactions Towards the Synthesis of Stereoisomers of Dipicolylamine Complexes. S. Raje, S. Gurusamy, A. Koner, S. Mehrotra, S. J. Jennifer, P. G. Vasudev, R. J. Butcher, R. Angamuthu. Chem. Asian. J., 2016, 11, 128-135. 

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Benzothiazoline Converts SO2 to Sulfuric Acid en Route to Benzothiazole. S. Mehrotra, R. J. Butcher, R. Angamuthu. ACS Sustainable Chem. Eng., 2016, 6517−6523. 


[8]  R. Angamuthu, C.-S. Chen, T. R. Cochrane, D. L. Gray, D. Schilter, O. A. Ulloa, T. B. Rauchfuss. N-Substituted Derivatives of the Azadithiolate Cofactor from the [FeFe] Hydrogenases: Stability and Complexation. Inorg. Chem. 2015, 54, 5717-5724.

[7]  G. M. Chambers, R. Angamuthu, D. L. Gray, T. B. Rauchfuss. Organo Ruthenium–Nickel Dithiolates with Redox-Responsive Nickel Sites. Organometallics 2013, 32, 6324-6329.

[6]  R. Angamuthu, M. E. Carroll, M. Ramesh, T. B. Rauchfuss. A New Route to Azadithiolato Complexes. Eur. J. Inorg. Chem. 2011, 1029-1032.


PhD (Leiden, NL)

[5]  R. Angamuthu, P. Byers, M. Lutz, A. L. Spek, E. Bouwman. Electrocatalytic carbon dioxide Conversion to Oxalate by a Copper Complex. Science 2010, 327, 313-315.

[4]  R. Angamuthu, L. L. Gelauff, M. A. Siegler, A. L. Spek, E. Bouwman. A molecular cage of nickel(II) and copper(I): a [{Ni(L)2}2(CuI)6] cluster resembling the active site of nickel-containing enzymes. Chem. Commun. 2009, 2700-2702.

[3]  R. Angamuthu, E. Bouwman. Reduction of protons assisted by a hexanuclear nickel thiolate metallacrown: protonation and electrocatalytic dihydrogen evolution. Phys. Chem. Chem. Phys. 2009, 11, 5578-5583.

[2]  R. Angamuthu, H. Kooijman, M. Lutz, A. L. Spek, E. Bouwman. Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks.  Dalton Trans. 2007, 4641-4643.


MSc (Bharathidasan, Trichy)

[1]  R. Angamuthu, R. Venugopal, U. M. Palanisamy, B. Ramalingam, C. A. Kilner, M. A. Halcrow, P. Mallayan. Copper(II) complexes of tridentate pyridylmethylethylenediamines: Role of ligand steric hindrance on DNA binding and cleavage. J. Inorg. Biochem. 2005, 99, 1717-1732.