Publications

Selected Publications

Late-stage Ligand Modification After Coordination Strengthens Stereoselectively Self-Assembled Hemiaminal Ether Complexes 

S. Raje, A. Koner, S. Ghosh, R. J. Butcher, L. Mathivathanan, M. Sundararajan, R. Angamuthu*

Chem. Asian. J. 2023, e202300706.

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Triazine-based eccentric Piedfort units towards a single source hydrogen-bonded network. 

S. Mehrotra, S. Raje, A. K. Jain, R. J. Butcher and  R. Angamuthu*

Chem. Commun., 2022, 58, 11815–11818. 

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Investigating the photosensitivity of koneramines for cell imaging and therapeutic applications.

S. Ghosh,*  A. Akhir,  D. Saxena, S. Singh, S. Sivakumar, S. Chopra* and  R. Angamuthu* 

Dalton Trans., 2022, 51, 15659 – 15668.

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Binding enabled catalytic activation of SO2 by copper koneramine complexes under ambient conditions.

M. Chahal, S. Raje,* G. Kotana and R. Angamuthu*

Green Chemistry, 2019, 21, 6372-6380. 

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Reductive Coupling of Bridging Diaryl Ligands in Half-Sandwich Cobalt(II) Dimers: Revisiting Triple-Decker Cobalt(I) Complexes.

S. Zhang, Y. Song, X. He, R. Angamuthu,* C.-H. Tung, and W. Wang*

Organometallics 2019, 38, 3610-3616.

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Solvent-Free Synthesis and Reactivity of Nickel(II) Borohydride and Nickel(II) Hydride. 

S. Raje* and R. Angamuthu* 

Green Chemistry, 2019, 21, 2752.

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Bioinspired Oxidative Cleavage of Aliphatic C-C Bond Utilizing Aerial Oxygen by Nickel Acireductone Dioxygenase Mimics. 

S. Raje, K. Mani, P. Kandasamy, R. J. Butcher and R. Angamuthu* 

Eur. J. Inorg. Chem. 2019, 2164–2167

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Mechanism of Evolution of Koneramine Complexes from One‐Pot Reactions: Snapshots of Intermediates Offer Facile Routes to New Dipicolylamines. 

S. Raje, N. Mondivagu, M. Chahal, R. J. Butcher, R. Angamuthu*

Chem. Asian. J., 2018, 13, 1458-1466. 

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Nickel-Mediated Stepwise Transformation of CO to Acetaldehyde and Ethanol. 

A. Zhang, S. Raje, J. Liu, X. Li, R. Angamuthu, C.-H. Tung, W. Wang* 

Organometallics, 2017, 3135−3141. 

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Benzimidazolines Convert Sulfur Dioxide to Bisulfate at Room Temperature and Atmospheric Pressure Utilizing Aerial Oxygen. 

S. Mehrotra, S. Raje, A. K. Jain, R. Angamuthu* 

ACS Sustainable Chem. Eng., 2017, 5, 6322-6328. 

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Synthetic [NiFe] models with a fluxional CO ligand. 

X. Chu, X. Yu, S. Raje, R. Angamuthu, J. Ma, C.-H. Tung, W. Wang* 

Dalton Trans.,2017, 46, 13681-13685.

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Multicomponent One-pot Reactions Towards the Synthesis of Stereoisomers of Dipicolylamine Complexes. 

S. Raje, S. Gurusamy, A. Koner, S. Mehrotra, S. J. Jennifer, P. G. Vasudev, R. J. Butcher, R. Angamuthu* 

Chem. Asian. J., 2016, 11, 128-135. 

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Benzothiazoline Converts SO2 to Sulfuric Acid en Route to Benzothiazole.

S. Mehrotra, R. J. Butcher, R. Angamuthu* 

ACS Sustainable Chem. Eng.,2016, 6517−6523. 

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PDF (University of Illinois at Urbana-Champaign; Prof. Thomas B. Rauchfuss)

R. Angamuthu, C.-S. Chen, T. R. Cochrane, D. L. Gray, D. Schilter, O. A. Ulloa, T. B. Rauchfuss*

N-Substituted Derivatives of the Azadithiolate Cofactor from the [FeFe] Hydrogenases: Stability and Complexation.

Inorg. Chem. 2015, 54, 5717-5724.

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G. M. Chambers, R. Angamuthu, D. L. Gray, T. B. Rauchfuss* 

Organo Ruthenium–Nickel Dithiolates with Redox-Responsive Nickel Sites. 

Organometallics 2013, 32, 6324-6329.

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R. Angamuthu, M. E. Carroll, M. Ramesh, T. B. Rauchfuss* 

A New Route to Azadithiolato Complexes.

Eur. J. Inorg. Chem. 2011, 1029-1032.

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PhD (Leiden University, The Netherlands; Profs Jan Reedijk and Elisabeth Bouwman)

R. Angamuthu, P. Byers, M. Lutz, A. L. Spek, E. Bouwman* 

Electrocatalytic carbon dioxide Conversion to Oxalate by a Copper Complex. 

Science 2010, 327, 313-315.

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R. Angamuthu, L. L. Gelauff, M. A. Siegler, A. L. Spek, E. Bouwman* 

A molecular cage of nickel(II) and copper(I): a [{Ni(L)2}2(CuI)6] cluster resembling the active site of nickel-containing enzymes. 

Chem. Commun. 2009, 2700-2702.

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R. Angamuthu, E. Bouwman* 

Reduction of protons assisted by a hexanuclear nickel thiolate metallacrown: protonation and electrocatalytic dihydrogen evolution. 

Phys. Chem. Chem. Phys. 2009, 11, 5578-5583.

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R. Angamuthu, H. Kooijman, M. Lutz, A. L. Spek, E. Bouwman* 

Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks.  

Dalton Trans. 2007, 4641-4643.

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MSc (Bharathidasan University, Tiruchirappalli; Prof. Mallayan Palaniandavar)

R. Angamuthu, R. Venugopal, U. M. Palanisamy, B. Ramalingam, C. A. Kilner, M. A. Halcrow, P. Mallayan*

Copper(II) complexes of tridentate pyridylmethylethylenediamines: Role of ligand steric hindrance on DNA binding and cleavage.

J. Inorg. Biochem. 2005, 99, 1717-1732.

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